Carbo-cyclohexadienes vs. carbo-benzenes: structure and conjugative properties
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چکیده
منابع مشابه
Carbo-cyclohexadienes vs. carbo-benzenes: structure and conjugative properties.
Ideally Cs-/C2v-symmetric chromophores, constituted by two electro-active groups conjugated through the carbo-mer of the cyclohexa-1,3-diene core, are selectively prepared by the SnCl2-mediated reduction of tailored hexaoxy-[6]pericyclynes: in the latter substrates, one of the 1,4-dioxybut-2-yne edges is "chemically locked" by two CF3 substituents preventing complete reduction to the correspond...
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متن کاملCarbo-cyclohexadienes vs. carbo-benzenes: structure and conjugative properties† †The investigations presented in this report have been performed within the framework of the French-Ukrainian GDRI “Groupement Franco-Ukrainien en Chimie Moléculaire” funded by the CNRS. ‡ ‡Electronic supplementary information (ESI) available: Experimental details, spectroscopic and crystallographic data. CCDC 1003439, 951896 and 951897. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02742f Click here for additional data file. Click here for additional data file.
[a] CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4 (France) [b] Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4 (France) [c] Kiev National Taras Shevchenko University, 60 Volodymlyrska St, 01033 Kiev (Ukraine) [d] Université de Toulouse, UPS, Institut de Chimie de Toulouse, ICT-FR 2599, 118 route de Narbonne, 31062 Toulou...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c4sc02742f